Preheat your oven to 170ºC (340ºF) and prepare three 20 cm (8-inch) round cake pans by lining with parchment paper and greasing the sides.

In a large bowl, sift together all-purpose flour, cornstarch, granulated sugar, dark brown sugar, cocoa powder, baking powder, baking soda, and salt.

In a separate bowl, whisk together the cooled black coffee, vegetable oil, sour cream, large eggs, and vanilla extract until smooth.

Gradually mix the wet ingredients into the dry ingredients until just combined, being careful not to overmix.

Divide the batter among the prepared cake pans and bake for 28-30 minutes. Check doneness with a toothpick.

Let the cakes cool in the pans for about 5 minutes, then invert onto a wire rack to cool completely.

In a stand mixer, beat softened butter until fluffy, then gradually add powdered sugar, vanilla, and instant espresso powder until light and airy.

Level the top of each cake layer and frost the top of each with coffee buttercream before stacking and frosting the sides.